Graphene, the wonder material, which has proved that it is by far one of the most versatile materials we have come across – through its use in weaving ultra strong silk webs; abilities that could pave way for faster processors; energy efficiency; its display abilities; and its long list of feature set – has yet again proven its mettle by proving itself useful in creation of world’s thinnest light bulb.
A team with members from multiple universities and institutes have managed to engineer – for the first time ever – a light bulb using graphene in the form of small strips attached to metal electrodes and suspended above the substrate. When current is passed through the filaments, they heat up and hence emit bright visible light.
Led by Young Duck Kim, a postdoctoral research scientist in James Hone’s group at Columbia Engineering, a team of scientists from Columbia, Seoul National University (SNU), and Korea Research Institute of Standards and Science (KRISS) reported their findings in a paper entitled ‘Bright visible light emission from graphene,’ is published in the Advance Online Publication (AOP) on Nature Nanotechnology’s website.
Hone, Wang Fon-Jen Professor of Mechanical Engineering at Columbia Engineering and co-author of the study is optimistic about the discovery as having the potential of paving way for graphene-based on-chip optical communications by integrating the new light emitter into chips.
One of the basic requirements of developing a fully integrated ‘photonic’ circuit and using light to carry out communications is the need of fitting a light source onto a chip. This is something scientists haven’t been able to do till now. Through researchers have developed many approaches to do this, they haven’t yet been able to put the oldest and simplest artificial light source — the incandescent light bulb — onto a chip.
The reason? It is because light bulb filaments must be extremely hot — thousands of degrees Celsius — in order to glow in the visible range and micro-scale metal wires cannot withstand such temperatures. In addition, heat transfer from the hot filament to its surroundings is extremely efficient at the microscale, making such structures impractical and leading to damage of the surrounding chip.
This is where graphene helped. By measuring the spectrum of the light emitted from the graphene, the team was able to show that the graphene was reaching temperatures of above 2500 degrees Celsius, hot enough to glow brightly. ‘The visible light from atomically thin graphene is so intense that it is visible even to the naked eye, without any additional magnification,’ explains Young Duck Kim, first and co-lead author on the paper and postdoctoral research scientist who works in Hone’s group at Columbia Engineering.
Interestingly, the spectrum of the emitted light showed peaks at specific wavelengths, which the team discovered was due to interference between the light emitted directly from the graphene and light reflecting off the silicon substrate and passing back through the graphene. Kim notes, ‘This is only possible because graphene is transparent, unlike any conventional filament, and allows us to tune the emission spectrum by changing the distance to the substrate.’
The ability of graphene to achieve such high temperatures without melting the substrate or the metal electrodes is due to another interesting property: as it heats up, graphene becomes a much poorer conductor of heat. This means that the high temperatures stay confined to a small ‘hot spot’ in the center.
“At the highest temperatures, the electron temperature is much higher than that of acoustic vibrational modes of the graphene lattice, so that less energy is needed to attain temperatures needed for visible light emission,” Myung-Ho Bae, a senior researcher at KRISS and co-lead author, observes. “These unique thermal properties allow us to heat the suspended graphene up to half of temperature of the sun, and improve efficiency 1000 times, as compared to graphene on a solid substrate.”
The team also demonstrated the scalability of their technique by realizing large-scale of arrays of chemical-vapor-deposited (CVD) graphene light emitters.
Yun Daniel Park, professor in the department of physics and astronomy at Seoul National University and co-lead author, notes that they are working with the same material that Thomas Edison used when he invented the incandescent light bulb: ‘Edison originally used carbon as a filament for his light bulb and here we are going back to the same element, but using it in its pure form — graphene — and at its ultimate size limit — one atom thick.’
The group is currently working to further characterize the performance of these devices — for example, how fast they can be turned on and off to create ‘bits’ for optical communications — and to develop techniques for integrating them into flexible substrates.
Hone adds, ‘We are just starting to dream about other uses for these structures — for example, as micro-hotplates that can be heated to thousands of degrees in a fraction of a second to study high-temperature chemical reactions or catalysis.’